
TY  - JOUR
A1  - Buckingham, DA 
A1  - Clark, CR 
T1  - Metal-hydroxide promoted hydrolysis of activated esters. Hydrolysis of 2,4-dinitrophenyl acetate and 4-nitrophenyl acetate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 2
SP  - 431
EP  - 436
KW  - 
UR  - https://doi.org/10.1071/CH9820431 
N2  - A range of exchange-labile and non-labile metal-hydroxide species readily promote the hydrolyses of 2,4-dinitrophenyl acetate and 4-nitrophenyl acetate. Kinetic studies (25ºC, I 1.0 mol dm-3 NaClO4) show that these processes follow shallow Bronsted slopes (&#946; 0.33 and 0.40 respectively) which extend over a range of 1010 in nucelophile basicity. A correlation is reported which allows the prediction of reaction rates between [CO(NH3)5OH]2+ and other activated charge-neutral carbonyl compounds. 
ER  -

