
TY  - JOUR
A1  - Coxon, JM 
A1  - Patsalides, E 
T1  - Photolysis of Di-t-butylnitroxide
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 3
SP  - 509
EP  - 515
KW  - 
UR  - https://doi.org/10.1071/CH9820509 
N2  - Di-t-butylnitroxide (1) on photolysis in methylcyclohexane gives in addition to t-butoxy(di-t-buty1)-amine (7) and photolabile 2-methyl-2-nitrosopropane (2) a low yield of a white crystalline solid identified as a mixture of di-t-butylhydroxylammonium nitrate (13) and nitrite (14). Photolysis proceeds from the excited state produced by a &#960;-&#960;* transition, and in aerated solution is first order both with respect to nitroxide and light intensity. More complex kinetics are observed in deaerated solution. 
ER  -

