
TY  - JOUR
A1  - Copeland, C 
A1  - Stick, RV 
T1  - The reaction of N-dichloromethylene-N,N-dimethylammonium chloride (Viehe's salt) with some carbohydrate diols
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 3
SP  - 581
EP  - 589
KW  - 
UR  - https://doi.org/10.1071/CH9820581 
N2  - The reaction of Viehe's salt (Me2N+=CCl2Cl-) with various carbohydrate diols (manno, allo) in the presence of a base is reported, the products being, after hydrolysis, either carbonate (with pyridine) or the carbamate (with triethylamine). A rationalization of the two different types of product formed is given in terms of the stereoelectronic control proposal by Deslongchamps. 
ER  -

