
%0 Journal Article
%A Brown, RD 
%A Godfrey, PD 
%A Winkler, DA 
%T Hyperfine interactions in methanimine
%J Australian Journal of Chemistry
%D 1982/04/01
%V 35
%N 4
%P 667-672
%K 
%R https://doi.org/10.1071/CH9820667
%U https://www.publish.csiro.au/paper/CH9820667 
%X A high-resolution study of hyperfine splitting in the microwave spectrum of methanimine has yielded the following values (in MHz) for 14N hyperfine constants: xaa- 0.898(8), xbb - 2.693(8), xcc 3.591(8), Ca -0.0495(47), Cb - 0*0097(27), Cc -0.0012(24). The localized theory for calculation of the magnetic hyperfine constants appears generally to overestimate Cc by an order of magnitude for molecules structurally similar to methanimine. 
