
%0 Journal Article
%A Colton, R 
%A Kevekordes, J 
%T Carbonyl halides of the Group VI transition metals. XXVII. Carbon-13 N.M.R. studies on molybdenum compounds
%J Australian Journal of Chemistry
%D 1982/05/01
%V 35
%N 5
%P 895-901
%K 
%R https://doi.org/10.1071/CH9820895
%U https://www.publish.csiro.au/paper/CH9820895 
%X Carbon-13 nuclear magnetic resonance studies have been carried out on a number of molybdenum(II) carbonyl halide species. It has been found that for these seven-coordinate capped octahedral complexes there is a very large shift to high frequency for a carbonyl group in the capping position. Thus carbon-13 n.m.r. provides a useful tool to distinguish between possible isomers. Trends in stability and isomer formation previously suspected from circumstantial evidence can now be rationalized. 
