
%0 Journal Article
%A Teitei, T 
%T Lactonization of o-Arylethenylbenzoic acids: Formation of 3,4-dihydro- 1 H-2-benzopyran-1-ones and isobenzofuran- 1(3H)-ones
%J Australian Journal of Chemistry
%D 1982/06/01
%V 35
%N 6
%P 1231-1235
%K 
%R https://doi.org/10.1071/CH9821231
%U https://www.publish.csiro.au/paper/CH9821231 
%X The formation of six 3,4-dihydro-1H-2-benzopyran-1-ones (2a-f) and one isobenzofuran-1(3H)-one (3a) from o-arylethenylbenzoic acids (1) in neutral or acid solution is described. The benzoic acids having a neutral or electron-releasing group on the double bond give &#948;-lactones (2), whereas compounds with a strong electron-withdrawing group give the &#947;-lactones (3). The mechanism is discussed in terms of electronic effects. The rate of cyclization of the (Z)-compound is found to be faster than that of the (E)-compound. 
