
TY  - JOUR
A1  - Down, GJ 
T1  - Improved synthesis of 2,10-dioxatricyclo[4,4,4,0<sup>1,6</sup>]tetradecanes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 6
SP  - 1269
EP  - 1272
KW  - 
UR  - https://doi.org/10.1071/CH9821269 
N2  - Cyanoethylation of substituted cyclohexanones at low temperatures has been found to give markedly improved yields and regioselectivity over the usual conditions for the Michael reaction. This reaction greatly facilitated the preparation of the 2,10-dioxatricyclo[4,4,4,01.6]tetradecanes (1). Carbon-13 n.m.r. data are reported for several substituted ketone and acetal intermediates and for the tricyclic acetal product (1b). 
ER  -

