
TY  - JOUR
A1  - May, GL 
A1  - Pinhey, JT 
T1  - The chemistry of aryllead(IV) tricarboxylates. Reaction with enamines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1982
VL  - 35
IS  - 9
SP  - 1859
EP  - 1871
KW  - 
UR  - https://doi.org/10.1071/CH9821859 
N2  - The treatment of 1-morpholinocyclopentene (la) with p-methoxyphenyllead triacetate (2a) in chloroform provides a simple high-yielding route to 2-(4-methoxyphenyl)cyclopentanone (3a). This arylation reaction of enamines has been investigated with a variety of substrates and a number of aryllead triacetates. The reaction has been found to be very sensitive to steric effects and is thus a useful synthetic method in a relatively small number of cases. Acetoxylation is a major competing reaction with those enamines of cyclic ketones which give a low to moderate yield of arylated product. 
ER  -

