
%0 Journal Article
%A Gheller, SF 
%A Hambley, TW 
%A Traill, PR 
%A Brownlee, RTC 
%A O'Conner, MJ 
%A Snow, MR 
%A Wedd, AG 
%T Applications of molybdenum-95 N.M.R. spectroscopy. VI. <sup>95</sup>Mo and <sup>13</sup>C N.M.R. of certain <I>cis</I>-dioxomolybdenum(VI) compounds and related species. The crystal and molecular structure of Bis(N,N-diethylhydroxylamido(l -)-O,N)- disulfidomolybdenum(VI) hemibenzene
%J Australian Journal of Chemistry
%D 1982/11/01
%V 35
%N 11
%P 2183-2191
%K 
%R https://doi.org/10.1071/CH9822183
%U https://www.publish.csiro.au/paper/CH9822183 
%X The 95MO n.m.r. spectra of a series of compounds containing the fac-[MoVIO3] and cis-[ MoVIO2] units are reported, together with those for the series [MoX2(R2NO)2] (X = O or S; R = Et, PhCH2). Trends in the data are discussed. The stereochemistry in solution of certain of the cis-dioxo species is assigned by means of 13C n.m.r. spectroscopy. The crystal and molecular structure of [MoS2(Et2NO)2],0.5C6H6 has been determined by X-ray crystallography. The steric and electronic requirements of the terminal sulfide ligands significantly affect the detailed coordination geometry relative to that observed for the dioxo analogue [MoO2(Et2NO)2]. Crystal data: a 10.162(2), b 11.836(2), c 14.437(2) Å, &#946; 106.12(2)º P21/a; Z 4. 
