
%0 Journal Article
%A Copeland, C 
%A Stick, RV 
%T The reaction of N-dichloromethylene-N,N-dimethylammonium chloride (Viehe's salt) with 1,2:5,6-di-O-isopropylidene-a-D-glucose
%J Australian Journal of Chemistry
%D 1982/11/01
%V 35
%N 11
%P 2269-2275
%K 
%R https://doi.org/10.1071/CH9822269
%U https://www.publish.csiro.au/paper/CH9822269 
%X The treatment of 1,2:5,6-di-O-isopropylidene-&#945;-D-glucose with N-dichloromethylene-N,N-dimethyl ammonium chloride (Viehe's salt) (2: 1 or 1 : 1) gives two iminium salts. These are readily hydrolysed to a carbonate and a carbamate. Treatment with sodium hydrogen sulfide gave some thiocarbonate and thiocarbamate. One of the iminium salts underwent a base-induced elimination to give 3-deoxy-1,2:5,6-di-O-isopropylidene-&#945;-D-ribo-hex-3-enofuranose. 
