
TY  - JOUR
A1  - Pinhey, JT 
A1  - Rowe, BA 
T1  - The chemistry of aryllead(IV) tricarboxylates. Reaction with &#945;-hydroxymethylene ketones : a route to &#945;-arylated ketones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1983
VL  - 36
IS  - 4
SP  - 789
EP  - 794
KW  - 
UR  - https://doi.org/10.1071/CH9830789 
N2  - &#945;-Hydroxymethylene ketones have been shown to react with aryllead triacetates in tetrahydrofuran containing pyridine to give &#945;-aryl &#945;-formyl ketones, unstable compounds, which were hydrolysed directly with alkali to &#945;-aryl ketones. The procedure has been used to produce in good yield 2-(p-methoxyphenyl)cyclohexanone, 2-(p-tolyl)cyclohexanone and the corresponding derivatives of4-t-butylcyclohexanone, and 2&#945;-(p-methoxypheny1)-5&#945;-cholestan-3-one and 3&#946;-hydroxy-16&#945;-(pmethoxypheny1)-5&#945;-androstan-17-one. 
ER  -

