
TY  - JOUR
A1  - Fergusson, JE 
A1  - Rankin, DA 
T1  - The chloro and bromo complexes of iridium(III) and iridium(IV). I. Preparation
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1983
VL  - 36
IS  - 5
SP  - 863
EP  - 869
KW  - 
UR  - https://doi.org/10.1071/CH9830863 
N2  - The chloro and bromo salts A2 [IrX6] (A = K, NH4, Rb, Cs; X = Cl, Br), A3 [IrCl6].H2O (A = K, NH4, Rb, Cs), A3 [IrCl6] (A = K, NH4), A2 [IrCl5H2O] (A = Rb, CS), (H3O)K8- [IrBr6]3.9H2O, A3 [IrBr6].H2O (A = NH4, Rb, CS), A3 [Ir2C19] (A = Rb, CS), A3 [Ir2Br9] (A = Rb, Cs, Me4N) and [Co(NH3)6] [IrX6] (X = Cl, Br) have been prepared and the various reaction paths studied. The ready oxidation of IrIII to IrIV and the equilibrium between IrIII monoiridium and diiridium bromo species means many reactions give a mixture of complexes. 
ER  -

