
%0 Journal Article
%A Bruce, MI 
%A Williams, ML 
%A Patrick, JM 
%A White, AH 
%T Cyclopentadienyl-ruthenium and -osmium chemistry. XXI. Synthesis and X-ray structure of OsCl(PPh<sub>3</sub>)<sub>2</sub>(&#951;-C<sub>5</sub>H<sub>5</sub>).CH<sub>2</sub>Cl<sub>2</sub>. Some structural comparisons of ruthenium-osmium pairs
%J Australian Journal of Chemistry
%D 1983/07/01
%V 36
%N 7
%P 1353-1359
%K 
%R https://doi.org/10.1071/CH9831353
%U https://www.publish.csiro.au/paper/CH9831353 
%X The X-ray structure of the CH2Cl2-solvate of OsCl(PPh3)2(&#951;-C5H5) has been determined, and compared with that of the non-solvated ruthenium analogue. Crystal are triclinic, space group P1, with a 14.490(3), b 14.110(3), c 9.937(3) Å, &#945; 99.84(2), &#946; 106.57(2), &#947; 100.08(2)º and Z 2. Refinement of 5297 data with I > 3&#963;(I) converged with R 0.033, R' 0.038. The Os-C and Os-Cl distances are c.0.007 Å longer than corresponding Ru-C and Ru-Cl distances, while the Os-P separations are 0.017 Å shorter than the Ru-P separations. 
