
TY  - JOUR
A1  - Bruce, MI 
A1  - Williams, ML 
A1  - Patrick, JM 
A1  - White, AH 
T1  - Cyclopentadienyl-ruthenium and -osmium chemistry. XXI. Synthesis and X-ray structure of OsCl(PPh<sub>3</sub>)<sub>2</sub>(&#951;-C<sub>5</sub>H<sub>5</sub>).CH<sub>2</sub>Cl<sub>2</sub>. Some structural comparisons of ruthenium-osmium pairs
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1983
VL  - 36
IS  - 7
SP  - 1353
EP  - 1359
KW  - 
UR  - https://doi.org/10.1071/CH9831353 
N2  - The X-ray structure of the CH2Cl2-solvate of OsCl(PPh3)2(&#951;-C5H5) has been determined, and compared with that of the non-solvated ruthenium analogue. Crystal are triclinic, space group P1, with a 14.490(3), b 14.110(3), c 9.937(3) Å, &#945; 99.84(2), &#946; 106.57(2), &#947; 100.08(2)º and Z 2. Refinement of 5297 data with I > 3&#963;(I) converged with R 0.033, R' 0.038. The Os-C and Os-Cl distances are c.0.007 Å longer than corresponding Ru-C and Ru-Cl distances, while the Os-P separations are 0.017 Å shorter than the Ru-P separations. 
ER  -

