
%0 Journal Article
%A Figgis, BN 
%A Kucharski, ES 
%A White, AH 
%T Crystal structure of Bis(2,2':6',2''-terpyridyl)cobalt(III) chloride
%J Australian Journal of Chemistry
%D 1983/08/01
%V 36
%N 8
%P 1563-1571
%K 
%R https://doi.org/10.1071/CH9831563
%U https://www.publish.csiro.au/paper/CH9831563 
%X The crystal structure of the title compound [CO(C15H11N3)2]Cl3 has been determined by single crystal X-ray diffraction methods at 295 K and refined by least-squares methods to a residual of 0.069 for 2953 'observed' reflections. Crystals are triclinic, PI, a 9.018(4), b 11.751(4), c 18.085(6)Å, &#945; 9O.82(6), &#946; 9O.66(7), &#947; 90.79(7)º, Z 2. The determination establishes for the first time metal-nitrogen distances in the bis(terpyridyl)cobalt(III) species; (Co-N)(central, distal) are 1.86, 1.93 Å. The precision of the determination is adversely affected by widespread solvent/anion disorder. 
