
%0 Journal Article
%A Healy, PC 
%A Patrick, JM 
%A Skelton, BW 
%A White, AH 
%T Structural studies in the iron(III)/chloride/&#945;,&#945;'-diimine system. I. The six-coordinate mononuclear <I>fac</I>-[FeCl<sub>3</sub>(phen)X] system, X = MeOH, H<sub>2</sub>O, Cl<sup>-</sup>
%J Australian Journal of Chemistry
%D 1983/10/01
%V 36
%N 10
%P 2031-2041
%K 
%R https://doi.org/10.1071/CH9832031
%U https://www.publish.csiro.au/paper/CH9832031 
%X The crystal structures of three iron complexes [FeCI3(phen)(MeOH)].MeOH (I), [FeCl3(phen)(H2O)] (2) and [phenH]+ [FeCl4(phen)]- (3) have been determined by single-crystal X-ray diffraction methods at 295(1) K, and refined by least squares to residuals of 0.044 (1600 'observed' reflections), 0.040 (806) and 0.050 (2496), respectively. Crystals of (1) are monoclinic, P21/c, a 8.005(9), b 14.805(11), c 14.830(12) A, P 101.03(7)&#176;, Z 4; for (2), triclinic, space group P1 , a 10.591(8), b 10.227(7), c 6.613(3) &#506;, &#945; 108.21(5), &#946; 100.69(5), &#947; 91.98(6)&#176;2, 2 ; for (3), triclinic, P1, a 18.560(8), b 10.302(5), c 6.981(3) &#506;, &#945; 106.79(4), &#946; 94.50(4), &#947; 103.15(4)&#176;, Z 2. In all structures, the iron atoms are six-coordinate, with the disposition of the three chlorine atoms being fac in (1) and (2). 
