
TY  - JOUR
A1  - Bapat, JB 
A1  - Durie, A 
T1  - Peracid oxidation of 1-pyrroline 1-oxides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 1
SP  - 211
EP  - 219
KW  - 
UR  - https://doi.org/10.1071/CH9840211 
N2  - Peracid oxidation of twelve 1-pyrroline 1-oxides (a class of cyclic nitrones) has been carried out.  Those compounds without a substituent in position 2 yielded the corresponding hydroxamic acids. 2-Phenyl-substituted 1-pyrroline 1-oxides gave nitro ketones, whereas 2-alkyl substituted 1-pyrroline 1-oxides gave nitroso ketones (as dimers) or nitro ketones. 2,4,4-Trimethyl-1-pyrroline 1-oxide gave an abnormal oxidation product, 2,4,4-trimethyl-1-pyrrolin-5-ol 1-oxide. Possible mechanisms of these reactions are discussed. 
ER  -

