
%0 Journal Article
%A Boyd, IW 
%A Wedd, AG 
%T Oxomolybdenum(V) complexes with Quinolin-8-olato, Quinoline-8-thiolato and Quinolin-8-aminato ligands
%J Australian Journal of Chemistry
%D 1984/02/01
%V 37
%N 2
%P 293-301
%K 
%R https://doi.org/10.1071/CH9840293
%U https://www.publish.csiro.au/paper/CH9840293 
%X The mononuclear complexes [MoVOXL2] (X = Cl, Br; LH = quinolin-8-ol, quinoline-8-thiol) have been synthesized from the reaction of (pyH)2 [MoOCl5] and (pyH) [MoOBr4] with quinolin-8-ol or 8-mercaptoquinolinium chloride and bromide in the presence of NEt3 or NaOMe. Bromine superhyperfine coupling [A(79,81Br) 7 &#215; 10-4 cm-1] is observed in the e.s.r. spectra of [MoOBrL2]. The reaction of (pyH)2 [MoOCl5] with quinolin-8-amine (LH) and water produces binuclear [Mo2O3Cl2L2]. 
