
TY  - JOUR
A1  - Hamann, SD 
T1  - A fallacy in some interpretations of the quasi-thermodynamics of reaction kinetics
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 4
SP  - 867
EP  - 869
KW  - 
UR  - https://doi.org/10.1071/CH9840867 
N2  - The fact that experimentally determined 'volumes of activation' and 'entropies of activation' obey a relationship that is formally similar to one of Maxwell's thermodynamic relations is a mathematicalconsequence of the definitions of those quantities. Contrary to suggestions in the literature, it provides no evidence in support of the quasi-thermodynamic and equilibrium assumptions of the transition state theory. 
ER  -

