
TY  - JOUR
A1  - Collins, DJ 
A1  - Drygala, PF 
A1  - Swan, JM 
T1  - Organophosphorus compounds. XXI. Solvolysis and C3-substitution reactions of some 2,3-Dihydro-1H-1,2-benzazaphosphole 2-oxides and 2-sulfides
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 6
SP  - 1349
EP  - 1356
KW  - 
UR  - https://doi.org/10.1071/CH9841349 
N2  - The solvolysis in D2O/CD3SOCD3 of the 2-phenyl-2,3-dihydro-1H-1,2-benzazaphosphole 2-oxides (5a-c), the analogous 2-methyl derivatives (6a-c), and of the 2-methyl-2,3-dihydro-lH-1,2-benzaza-phosphole 2-sulfides (6d) and (6e) was examined semi-quantitatively by n.m.r. spectroscopy. 1-Methyl-2-phenyl-2,3-dihydro-1 H-1,2-benzazaphosphole 2-oxide (5b) was subjected to reductive ring-opening reactions, base-catalysed C3-alkylation, and base-catalysed formation of a 3-benzylidene derivative. 
ER  -

