
%0 Journal Article
%A Bruce, MI 
%A Humphrey, MG 
%A Swincer, AG 
%A Wallis, RC 
%T Cyclopentadienyl-ruthenium and -osmium chemistry. XXIII. Synthesis and reactions of some hydrido complexes containing ruthenium or osmium, and related chemistry
%J Australian Journal of Chemistry
%D 1984/08/01
%V 37
%N 8
%P 1747-1755
%K 
%R https://doi.org/10.1071/CH9841747
%U https://www.publish.csiro.au/paper/CH9841747 
%X The hydrido complexes HM(PPh3)2(&#951;-C5H5) (M = Ru, Os), HFe(dppe)(&#951;-C5H5), HRu(L2)(&#951;-C5H5) (L2 = dppe, dppm or dpae), HRu(AsPh3),(&#951;-C5H5), HRu(L)(PPh3)(&#951;-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCI[P(OPh)3]2(&#951;-C5H5) affords the cyclometallated  Ru[(C6H4O)P(OPh)3)2][P(Oph)3]&#951;-C5H5) under these conditions. Reactions between HRu(PPh3)2(&#951; C5H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(&#951;-C5H5); CS2 reacts with HRuL2(&#951;-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(&#951; -C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200ºC in an autoclave. 
