
TY  - JOUR
A1  - Bruce, MI 
A1  - Humphrey, MG 
A1  - Swincer, AG 
A1  - Wallis, RC 
T1  - Cyclopentadienyl-ruthenium and -osmium chemistry. XXIII. Synthesis and reactions of some hydrido complexes containing ruthenium or osmium, and related chemistry
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 8
SP  - 1747
EP  - 1755
KW  - 
UR  - https://doi.org/10.1071/CH9841747 
N2  - The hydrido complexes HM(PPh3)2(&#951;-C5H5) (M = Ru, Os), HFe(dppe)(&#951;-C5H5), HRu(L2)(&#951;-C5H5) (L2 = dppe, dppm or dpae), HRu(AsPh3),(&#951;-C5H5), HRu(L)(PPh3)(&#951;-C5H5) [L = CNBut, P(OPh)3] have been obtained from reactions between the analogous chloro complexes and NaOMe/MeOH; RuCI[P(OPh)3]2(&#951;-C5H5) affords the cyclometallated  Ru[(C6H4O)P(OPh)3)2][P(Oph)3]&#951;-C5H5) under these conditions. Reactions between HRu(PPh3)2(&#951; C5H5) and HX or CHX3 (X = Cl, Br, I) afford the corresponding halo complexes RuX(PPh3)2(&#951;-C5H5); CS2 reacts with HRuL2(&#951;-C5H5) (L = PPh3, L2 = dppe) to give the corresponding dithioformato derivatives. Ligand-exchange reactions of HRu(PPh3)2(&#951; -C5H5) with CO or dppe proceed with difficulty at temperatures of c. 150-200ºC in an autoclave. 
ER  -

