
%0 Journal Article
%A Crow, WD 
%A Pang, YT 
%T Synthetic applications of intramolecular insertion in arylcarbenes. VI. Ylid rearrangements in pyrolysis of o-alkylthiophenylcarbenes
%J Australian Journal of Chemistry
%D 1984/09/01
%V 37
%N 9
%P 1903-1914
%K 
%R https://doi.org/10.1071/CH9841903
%U https://www.publish.csiro.au/paper/CH9841903 
%X Low-pressure thermal generation of a range of o-alkylthiophenylcarbenes produces, in addition to the normal insertion products, styrenes and 1,3-dihydrobenzo[c]thiophens-clearly arising from rearrangement. The main features of their mechanism of formation are established by deuterium-labelling studies: in both cases participation by S-ylids is implicated. 
