
TY  - JOUR
A1  - Crow, WD 
A1  - Pang, YT 
T1  - Synthetic applications of intramolecular insertion in arylcarbenes. VI. Ylid rearrangements in pyrolysis of o-alkylthiophenylcarbenes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1984
VL  - 37
IS  - 9
SP  - 1903
EP  - 1914
KW  - 
UR  - https://doi.org/10.1071/CH9841903 
N2  - Low-pressure thermal generation of a range of o-alkylthiophenylcarbenes produces, in addition to the normal insertion products, styrenes and 1,3-dihydrobenzo[c]thiophens-clearly arising from rearrangement. The main features of their mechanism of formation are established by deuterium-labelling studies: in both cases participation by S-ylids is implicated. 
ER  -

