
TY  - JOUR
A1  - Della, EW 
A1  - Pigou, PE 
A1  - Livett, MK 
A1  - Peel, JB 
T1  - The Photoelectron Spectrum of 1-Bromonortricyclene
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1985
VL  - 38
IS  - 1
SP  - 69
EP  - 75
KW  - 
UR  - https://doi.org/10.1071/CH9850069 
N2  - The He I photoelectron spectrum of 1-bromotricyclo[2.2.1.02.6] heptane (1- bromonortricyclene ) is compared with that of the parent alkane . Extensive conjugation between bromine and alkane orbitals in the low ionization-energy range produces a complex band pattern which is adequately described by ab initio valence-electron molecular orbital calculations. Consequently 1-bromo-nortricyclene presents a rare example of an alkyl halide in which the halogen character is neither highly localized nor smeared over a high density of states. 
ER  -

