
%0 Journal Article
%A Packer, JE 
%A Taylor, RER 
%T Free-Radical Reductions of Arenediazonium Ions in Aqueous Solution. VI. On Iododediazoniation
%J Australian Journal of Chemistry
%D 1985/06/01
%V 38
%N 6
%P 991-996
%K 
%R https://doi.org/10.1071/CH9850991
%U https://www.publish.csiro.au/paper/CH9850991 
%X &#947;-Irradiation of aqueous solutions of p-ClC6H4N2+BF4- and KI initiates a chain reaction in which dichloroazobenzene is the major product. When iodine is also present the chain reaction is longer and the major product is chloroiodobenzene . The reaction                              I2-&#183;+ArN2+ &#8594; I2+Ar&#183;+N2 is suggested to be propagation step in both reactions, with Ar &#183; reacting with I3- in the presence of iodine and with ArN2+ in its absence. The relevance of these reactions to iododediazoniation is discussed. 
