
TY  - JOUR
A1  - MacDermott, TE 
T1  - Synthesis of Some Novel Dinuclear Metal Complexes, Containing Both Square-Planar and Tetrahedral Metal Ions, by the Reactions of Coordinated Diamines with an &#945;-Hydroxy Ketone
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1985
VL  - 38
IS  - 9
SP  - 1319
EP  - 1324
KW  - 
UR  - https://doi.org/10.1071/CH9851319 
N2  - Reactions between tris (propane-1,3-diamine)nickel(II) salts and 3- hydroxy-3-methylbutan-2-one in the presence of zinc(II) or cadmium(II) halides yield a series of di -oxygen-bridged dinuclear products which contain the square-planar nickel(II) complex of a 12-membered ligand ring one of whose members is either a zinc(II) or cadmium(II) halide. These complexes are thermally very stable but may be hydrolysed by water to give a complex of the corresponding &#945;- imino alcohol. 
ER  -

