
TY  - JOUR
A1  - Dyason, JC 
A1  - Healy, PC 
A1  - Engelhardt, LM 
A1  - White, AH 
T1  - Lewis-Base Adducts of Group 1B Metal(I) Compounds. XXII. Crystal Structure of 'Bis(pyridine)silver(I) Perchlorate
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1985
VL  - 38
IS  - 9
SP  - 1325
EP  - 1328
KW  - 
UR  - https://doi.org/10.1071/CH9851325 
N2  - Determination of the crystal structure of 'bis (pyridine)silver(I) perchlorate' by single-crystal X-ray methods shows it to be of 2.4:1 pyridine:silver (I) perchlorate stoichiometry , the structure being refined by least squares to a residual of 0.054 for 1142 'observed' reflections. Crystals are tetragonal, I4, a 21.95(1), c 7.684(3) &#506;. The structure comprises perchlorate anions of two types of I and 4 symmetry, together with two types of complex cation: [Ag( py )2]+, with 1 symmetry, and [Ag( py )4]+ with 4 symmetry. For the two types of cation Ag-N are 2.15(1), 2.16(1) and 2.30(1) &#506;. 
ER  -

