
%0 Journal Article
%A Kildea, JD 
%A Skelton, BW 
%A White, AH 
%T Crystallographic Characterization of a Hydrated Form of Copper(I) Cyanide
%J Australian Journal of Chemistry
%D 1985/09/01
%V 38
%N 9
%P 1329-1334
%K 
%R https://doi.org/10.1071/CH9851329
%U https://www.publish.csiro.au/paper/CH9851329 
%X The crystal structure of a crystalline artefact of a reaction involving copper(I), cyanide and water under conditions of high temperature and pressure has been determined by single-crystal X-ray diffraction methods at 295 K, and refined by full matrix least-squares to a residual of 0.046 for 572 independent 'observed' reflections; the composition is suggested to be [Cu3(CN)3(H2O)]&#8734;, comprising a two- dimensional polymer with both linearly coordinated and bridging cyanide groups. Crystals are monoclinic, probable space group C2/c, a 19.048(7), b 6.798(3), c 13.223(7) &#506;, &#946; 125.72(3)&#176;, Z 8. 
