
%0 Journal Article
%A Engelhardt, LM 
%A Patrick, JM 
%A White, AH 
%T Crystal Structures of Bis(pyrrolidinedithiocarbamato)-nickel(II) and -copper(II) (Redeterminations)
%J Australian Journal of Chemistry
%D 1985/09/01
%V 38
%N 9
%P 1413-1416
%K 
%R https://doi.org/10.1071/CH9851413
%U https://www.publish.csiro.au/paper/CH9851413 
%X Single-crystal X-ray redeterminations of the title compounds have been carried out at 295 K, by using diffractometer , rather than film data. [Ni(S2CN(CH2)4)2], (1), and [Cu(S2CN(CH2)4)2], (2), are isomorphous and triclinic, p&#299; , with Z = 1, the metal atom being located on a crystallographic inversion centre. The structure of (1), a 7.470(2), b 7.972(3), c 6.325(3) &#506;, &#945; 103.17(3), &#946; 93.48(3)&#176;, &#947; 75.45(3)&#176;, yielded R 0.038 for 1041 independent 'observed' reflections; for (2), a 7.477(3), b 8.057(2), c 6.373(1) &#506;, &#945; 104.77(1), &#946; 94.06(2), &#947; 76.60(2)&#176;, R was 0.033 for 1037 reflections. Ni-S are 2.214(1), 2.198(1) &#506;; Cu-S are 2.312(1), 2.280(1) &#506;. 
