
TY  - JOUR
A1  - Jackson, WR 
A1  - Rae, ID 
A1  - Wong, MG 
T1  - The Stereochemistry of Organometallic Compounds .XXVII. Nucleophilic and Electrophilic Substitution-Reactions of Conformationally Restricted Arenechromium Compounds
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 2
SP  - 303
EP  - 315
KW  - 
UR  - https://doi.org/10.1071/CH9860303 
N2  - The regioselectivity of reaction of tricarbonyl (1,1- dimethylindane )chromium with selected electrophiles and nucleophiles has been shown to be influenced by the preferred conformation of the tricarbonylchromium group. Nucleophiles preferentially react at carbon atoms eclipsed by a chromium-carbonyl bond and electrophiles at carbon atoms in staggered positions. When similar reactions were attempted with some chelated  arenechromium dicarbonyl phosphorus compounds only low yields of substitution products were obtained. 
ER  -

