
%0 Journal Article
%A Mak, TCW 
%A Yip, WH 
%A Kennard, CHL 
%A Smith, G 
%A Oreilly, EJ 
%T The Crystal-Structure of Silver(I) (2-Carbamoylphenoxy)Acetate
%J Australian Journal of Chemistry
%D 1986/03/01
%V 39
%N 3
%P 541-546
%K 
%R https://doi.org/10.1071/CH9860541
%U https://www.publish.csiro.au/paper/CH9860541 
%X The crystal structure of anhydrous silver(I)(2-carbamoylphenoxy)acetate has been determined by X-ray diffraction and refined to a residual of 0.041 for 1532 observed reflections. The complex forms crystal: with space group C2/c and Z4 in a unit cell of dimensions a 20.789(6), b 5.202(1) c 17.318(6)&#506;, &#946; 105.89(2)&#176;. The structure is based on a centrosymmetric bis-carboxylate bridged dimer [Ag-O 2.228(3), 2.266(3)&#506;, O-Ag-O 155.8(1)&#176;; Ag&#8230;Ag 3.001(1)&#506;] which is extended into an infinite zigzag polymer through the axial positions via the carbamoyl oxygens of adjacent ligands [Ag-O 2.494(3)&#506;]. Symmetrical long-rang interactions of phenyl-carbon to silver are also found in the structure [Ag-C 3.094, 3.078(4)&#506;]. 
