
%0 Journal Article
%A Tiekink, ERT 
%A Winter, G 
%T The Crystal-Structure of Bis(O-Ethylxanthato)-Triphenylphosphinenickel(II) - Ni(S<sub>2</sub>COC<sub>2</sub>H<sub>5</sub>)<sub>2</sub>P(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>
%J Australian Journal of Chemistry
%D 1986/05/01
%V 39
%N 5
%P 813-816
%K 
%R https://doi.org/10.1071/CH9860813
%U https://www.publish.csiro.au/paper/CH9860813 
%X The crystal and molecular structure of the 1:1 adduct formed between bis (O- ethylxanthato )nickel(II) and triphenylphosphine is reported. The nickel atom is five-coordinate in a distorted square-pyramidal geometry with a sulfur atom, from an asymmetrically coordinating xanthate  ligand , in the apical position. Crystals are triclinic, space group P&#299;, a 10.265(4), b 14.718(5), c 8.818(4) &#506;, &#945; 100.77(3), &#946; 92.16(4), &#947; 89.56(3)&#176; with Z 2. The structure was refined by a least-squares method; R 0.068 for 3301 reflections with I &#8805; 3.0&#963;(I). 
