
%0 Journal Article
%A Belton, PS 
%A Cox, IJ 
%A Harris, RK 
%A Oconnor, MJ 
%T S-33 and O-17 N.M.R-Studies of Thiomolybdates and Thiotungstates
%J Australian Journal of Chemistry
%D 1986/07/01
%V 39
%N 7
%P 943-952
%K 
%R https://doi.org/10.1071/CH9860943
%U https://www.publish.csiro.au/paper/CH9860943 
%X Sulfur-33 and oxygen-17 n.m.r . studies are shown to have considerable potential in following the equilibration of the thiometallate anions [MSnO4-n]2- (M = W, Mo; n = 0-4) in aqueous solution. Chemical shift and linewidth data are presented for these ions. Variations in both the oxygen-17 and sulfur-33 shifts can be correlated with the lowest-energy electronic transition. Moreover, changes in the oxygen-17 and sulfur-33 chemical shift data can be correlated with the molybdenum-95 and tungsten-183 chemical shift values, which have been previously reported. The implications for the nature of the bonding in these anions are discussed. 
