
TY  - JOUR
A1  - Belton, PS 
A1  - Cox, IJ 
A1  - Harris, RK 
A1  - Oconnor, MJ 
T1  - S-33 and O-17 N.M.R-Studies of Thiomolybdates and Thiotungstates
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 7
SP  - 943
EP  - 952
KW  - 
UR  - https://doi.org/10.1071/CH9860943 
N2  - Sulfur-33 and oxygen-17 n.m.r . studies are shown to have considerable potential in following the equilibration of the thiometallate anions [MSnO4-n]2- (M = W, Mo; n = 0-4) in aqueous solution. Chemical shift and linewidth data are presented for these ions. Variations in both the oxygen-17 and sulfur-33 shifts can be correlated with the lowest-energy electronic transition. Moreover, changes in the oxygen-17 and sulfur-33 chemical shift data can be correlated with the molybdenum-95 and tungsten-183 chemical shift values, which have been previously reported. The implications for the nature of the bonding in these anions are discussed. 
ER  -

