
%0 Journal Article
%A Elliott, RL 
%A Nichols, PJ 
%A West, BO 
%T Synthesis of Heterobinuclear Oxo-Bridged Compounds of Chromium, Iron, Manganese and Molybdenum
%J Australian Journal of Chemistry
%D 1986/07/01
%V 39
%N 7
%P 975-985
%K 
%R https://doi.org/10.1071/CH9860975
%U https://www.publish.csiro.au/paper/CH9860975 
%X The synthesis of a series of heterobinuclear oxo -bridged compounds has been accomplished by redox reactions between FeII or MnII complexes of pentadentate and tetradentate salicylideneimines and thiosalicylideneimines and bidentate  dithiocarbamates and either CrIVO ( tpp )( tpp &#8801; dianion of 5,10,15,20-tetraphenylporphyrin) or MoVI (O)2( dtc )2 ( dtc &#8801; diethyldithiocarbamato anion). The compounds are stable in solution in the absence of air but yield various homonuclear derivatives of the metals in its presence, these results indicating a degree of disproportionation of the oxo complexes. The compounds show reduced magnetic moments in line with magnetic coupling between the metal centres. 
