
TY  - JOUR
A1  - Cavell, KJ 
A1  - Masters, AF 
T1  - Olefin Oligomerization and Isomerization Catalysts. The Preparation, Properties and Catalytic Action of Dithio Nickel(II) Complexes With Chelating Phosphines
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 7
SP  - 1129
EP  - 1134
KW  - 
UR  - https://doi.org/10.1071/CH9861129 
N2  - The syntheses and properties of cationic nickel complexes containing dithio-&#946;-diketonate and chelating bisphosphine ligands of general formula [Ni{R1C(S)CR2C(S)R3}{(PL1L2)R(PL3L4)}]X(Rj,Lj = alkyl or aryl, R = (CH2)n, n = 1-4, X = halide, BPh4, PF6, etc.) are described. The compounds are shown to be effective catalysts for the oligomerization and double bond shift isomerization of olefins with a high specificity for dimeric products rich in desirable linear and near linear isomers. 
ER  -

