
%0 Journal Article
%A Gainsford, GJ 
%A Jackson, WG 
%A Sargeson, AM 
%T Novel Synthesis and Structure of a Bridging Peroxo Pentaaminecobalt(III) Dimer
%J Australian Journal of Chemistry
%D 1986/09/01
%V 39
%N 9
%P 1331-1336
%K 
%R https://doi.org/10.1071/CH9861331
%U https://www.publish.csiro.au/paper/CH9861331 
%X The addition of excess glycine ethyl ester to Co{(H2NCH2CH2)3N}(OSMe2)23+ in Me2SO leads to the symmetrical dimeric  peroxo ion p,p - [Co( tren )(NH2CH2CO2Et)]2O24+ under mild conditions. The single-crystal X- ray structure of the perchlorate salt is described, and the mechanism for the dimer formation is considered. 
