
%0 Journal Article
%A Bruce, MI 
%A Duffy, DN 
%T Chemistry of the Group-1B Metals. XIX. Crystal and Molecular-Structures of (2-Phenylethynyl)(Triphenylphosphine)Gold(I), Au(C=CPh)(PPh<sub>3</sub>)
%J Australian Journal of Chemistry
%D 1986/10/01
%V 39
%N 10
%P 1697-1701
%K 
%R https://doi.org/10.1071/CH9861697
%U https://www.publish.csiro.au/paper/CH9861697 
%X The molecular structure of Au(C2Ph)(PPh3) consists a gold atom almost linearly coordinated by a phenylethynyl group [Au-C 1.97(2), 2.02(2)&#506;] and a PPh3 ligand [Au-P 2.276(5), 2.282(4)&#506;]; a weak Au&#8230;Au interaction [3.379(1)&#506;] holds the two independent molecules in a nearly orthogonal arrangement. Crystals are monoclinic, space group P21/c, with a 12.431(4), b 21.439(4), c 16.366(5)&#506;, &#946; 96.36(3)&#176;, Z 8; 1750 independent data with I &#8805; 2.5&#963;(I) were refined to R 0.033, Rw 0.035. 
