
%0 Journal Article
%A Broomhead, JA 
%A Greenwood, R 
%A Pienkowski, W 
%A Sterns, M 
%T Preparation, X-Ray Crystal-Structure and Properties of Pentacarbonyl-(Pyridinium-2-Thiolate)Tungsten(0)
%J Australian Journal of Chemistry
%D 1986/11/01
%V 39
%N 11
%P 1895-1900
%K 
%R https://doi.org/10.1071/CH9861895
%U https://www.publish.csiro.au/paper/CH9861895 
%X The title complex is prepared either photochemically from pyridine-2-thiol and W(CO)6 or thermally from WBr2(CO)4. The molecular structure of this air-stable, diamagnetic compound shows an octahedral environment for the metal. The ligand is sulfur-bound only and the pyridine nitrogen is protonated. Crystals are monoclinic, space group P21/c with a 722.8(1), b 1375.5(4), c 1306.7(2) pm, &#946; 98.815(5)&#176; V 1.2839(5)&#215;109 pm3 and Z 4; 2294 data were refined to R 0.026, Rw 0.032. 
