
TY  - JOUR
A1  - Hammershoi, A 
A1  - Lawrance, GA 
A1  - Sargeson, AM 
T1  - Redox Properties of Macrotricyclic Hexaamine Cobalt(III) Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1986
VL  - 39
IS  - 12
SP  - 2183
EP  - 2186
KW  - 
UR  - https://doi.org/10.1071/CH9862183 
N2  - Electrochemical properties of the macrocyclic  hexaamine cobalt(III) complex [Co( taetacn )]3+ and its macrotricyclic derivatives [Co( azasartacn )]3+, [Co( nosartacn )]3+, [Co( amsartacn )]3+, and [Co( amsartacnH )]4+ in water, acetonitrile and acetone are reported and compared with those of macrobicyclic analogues. The results show that the tricyclic cage complexes are reduced somewhat more readily than their bicyclic equivalents, implying that the cavity sizes for the tricyclic systems are somewhat larger. 
ER  -

