
%0 Journal Article
%A Broomhead, JA 
%A Enemark, JH 
%A Hammer, B 
%A Ortega, RB 
%A Pienkowski, W 
%T Synthesis and X-Ray Structural Characterization of WO(S<sub>2</sub>)(S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub> and Related Complexes
%J Australian Journal of Chemistry
%D 1987/02/01
%V 40
%N 2
%P 381-385
%K 
%R https://doi.org/10.1071/CH9870381
%U https://www.publish.csiro.au/paper/CH9870381 
%X The reaction of SO2 and W(CO)3(S2CNR2)2 in dichloromethane solution under dinitrogen gives the title complex along with WS(S2)(S2CNR2)2 and Syn-W2O2(µ-S)2(S2CNR2)2 (R = Me, Et, Pri , C6H5CH2; NR2 = pyrrolidinyl ). X-ray structural analysis of WO(S2)(S2CNEt2)2 reveals a seven-coordinate tungsten complex with a terminal oxo group and a dihapto - disulfido ligand in a mutually triangular arrangement. Crystals are monoclinic space group P21 1 n, with a 9.379(2), b 22.276(7), c 9.408(2), &#946; 106.86(1)º, U 188l.1(7) Å33 and Z 4.2758 independent data were refined to a weighted agreement factor 0.036. 
