
TY  - JOUR
A1  - Broomhead, JA 
A1  - Enemark, JH 
A1  - Hammer, B 
A1  - Ortega, RB 
A1  - Pienkowski, W 
T1  - Synthesis and X-Ray Structural Characterization of WO(S<sub>2</sub>)(S<sub>2</sub>CNEt<sub>2</sub>)<sub>2</sub> and Related Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1987
VL  - 40
IS  - 2
SP  - 381
EP  - 385
KW  - 
UR  - https://doi.org/10.1071/CH9870381 
N2  - The reaction of SO2 and W(CO)3(S2CNR2)2 in dichloromethane solution under dinitrogen gives the title complex along with WS(S2)(S2CNR2)2 and Syn-W2O2(µ-S)2(S2CNR2)2 (R = Me, Et, Pri , C6H5CH2; NR2 = pyrrolidinyl ). X-ray structural analysis of WO(S2)(S2CNEt2)2 reveals a seven-coordinate tungsten complex with a terminal oxo group and a dihapto - disulfido ligand in a mutually triangular arrangement. Crystals are monoclinic space group P21 1 n, with a 9.379(2), b 22.276(7), c 9.408(2), &#946; 106.86(1)º, U 188l.1(7) Å33 and Z 4.2758 independent data were refined to a weighted agreement factor 0.036. 
ER  -

