
TY  - JOUR
A1  - Cambie, RC 
A1  - Howe, TA 
A1  - Pausler, MG 
A1  - Rutledge, PS 
A1  - Woodgate, PD 
T1  - Experiments Directed Towards the Synthesis of Anthracyclinones .XIV. An Intermediate for the Synthesis of Vineomycins
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1987
VL  - 40
IS  - 6
SP  - 1063
EP  - 1072
KW  - 
UR  - https://doi.org/10.1071/CH9871063 
N2  - Anthrarufin (4) has been converted by a high-yielding route involving sequential reductive Claisen rearrangements into 1-acetoxy-5-methoxy-9,10-dioxo-6-(2'-oxopropy1)-9,10-dihydroanthracene-2-carbaldehyde (3), an intermediate which is suitable for the synthesis of vineomycins . The thermal Claisen rearrangements of some allyl ethers of 1,5-dihydroxyanthraquinone have been examined. 
ER  -

