
TY  - JOUR
A1  - Black, DS 
A1  - Chaichit, N 
A1  - Gatehouse, BM 
A1  - Moss, GI 
T1  - Metal Template Reactions. XXV. N-Acyl Isatin Precursors for the Synthesis of Malonamido Macrocyclic Metal Complexes
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1987
VL  - 40
IS  - 10
SP  - 1745
EP  - 1754
KW  - 
UR  - https://doi.org/10.1071/CH9871745 
N2  - Reaction of sodium isatide with dimethylmalonyl dichloride yielded the oxazinoindole (6) rather than the expected product (4). The glyoxylamide (8), which served as a precursor to the macrocyclic complex (15), was therefore prepared by a sequence involving compounds (9), (10) and (7). Such a route makes use of the reactivity of N-acyl isatins and the protecting capacity of the benzyloxycarbonyl group. The structure of compound (6) was established by X-ray crystallography. 
ER  -

