
%0 Journal Article
%A Healy, PC 
%A Kildea, JD 
%A White, AH 
%T Lewis-Base Adducts of Group 11 Metal(I) Compounds. XXIV. 1:2 Silver(I) Halide/Monodentate Amine Complexes: A Novel Structural Type in 1-2 Silver(I) Chloride Piperidine
%J Australian Journal of Chemistry
%D 1988/03/01
%V 41
%N 3
%P 417-418
%K 
%R https://doi.org/10.1071/CH9880417
%U https://www.publish.csiro.au/paper/CH9880417 
%X Recrystallization of silver(I) chloride from neat piperidine (L) yields a 1 : 2 adduct, characterized by a single-crystal X-ray study. Crystals are monoclinic, C2/c, a 20.76(4), b 6.422(7), c 20.69(2)&#506;, &#946; 96.9(1)&#176;, Z 8; R 0.042 for 1061 'observed' reflections. The structure, the first determined for a 1 : 2 silver(I) chloride/monodentate amine adduct, is an infinite one-dimensional chloro-bridged polymer -AgL2-Cl-AgL2-Cl-. About the four-coordinate silver atom, Ag-Cl are 2.524(3), 2.667(3)&#506;, Ag-N 2.385(9), 2.347(11)&#506;, with Ag-Cl-Ag 102.62(9)&#176;; the largest angle in the silver environment is 120.3(2)&#176;(Cl-Ag-N). 
