
%0 Journal Article
%A Haynes, RK 
%A Vonwiller, SC 
%A Stokes, JP 
%A Merlino, LM 
%T The Preparation of Some &#946;-Sulfonylacrylate Thioesters and &#946;-Sulfonylvinyl Ketones
%J Australian Journal of Chemistry
%D 1988/06/01
%V 41
%N 6
%P 881-895
%K 
%R https://doi.org/10.1071/CH9880881
%U https://www.publish.csiro.au/paper/CH9880881 
%X &#946;- Sulfonylacrylate phenyl and t-butyl thioesters , and &#946;- sulfonylvinyl  ketones have been prepared by oxidation of the corresponding &#946;-aryl- and &#946;-alkyl- thio compounds. In one case the &#946;- sulfonylvinyl ketone was obtained from an epoxy sulfone . The &#946;-aryl- and &#946;-alkyl- thio compounds were obtained by chlorination- dehydrochlorination of saturated precursors. The reactions of 3-( phenylthio ) propionyl chloride with organocadmium and Grignard reagents were used to prepare some of the saturated precursors of the &#946;- sulfonylvinyl  ketones. 
