
TY  - JOUR
A1  - Haynes, RK 
A1  - Vonwiller, SC 
A1  - Stokes, JP 
A1  - Merlino, LM 
T1  - The Preparation of Some &#946;-Sulfonylacrylate Thioesters and &#946;-Sulfonylvinyl Ketones
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 6
SP  - 881
EP  - 895
KW  - 
UR  - https://doi.org/10.1071/CH9880881 
N2  - &#946;- Sulfonylacrylate phenyl and t-butyl thioesters , and &#946;- sulfonylvinyl  ketones have been prepared by oxidation of the corresponding &#946;-aryl- and &#946;-alkyl- thio compounds. In one case the &#946;- sulfonylvinyl ketone was obtained from an epoxy sulfone . The &#946;-aryl- and &#946;-alkyl- thio compounds were obtained by chlorination- dehydrochlorination of saturated precursors. The reactions of 3-( phenylthio ) propionyl chloride with organocadmium and Grignard reagents were used to prepare some of the saturated precursors of the &#946;- sulfonylvinyl  ketones. 
ER  -

