
%0 Journal Article
%A Bruce, MI 
%A Butler, IR 
%A Cullen, WR 
%A Koutsantonis, GA 
%A Snow, MR 
%A Tiekink, ERT 
%T Cyclopentadienyl-Ruthenium and -Osmium Chemistry. XXXI. Preparation of Some Complexes Containing 1,1'-Bis(diphenylphosphino)ferrocene (dppf): X-Ray Structure of RuH(dppf)(&#951;-C<sub>5</sub>H<sub>5</sub>)
%J Australian Journal of Chemistry
%D 1988/06/01
%V 41
%N 6
%P 963-969
%K 
%R https://doi.org/10.1071/CH9880963
%U https://www.publish.csiro.au/paper/CH9880963 
%X Exchange of 2PPh3 for Fe(&#951;-C5H4PPh2)2 ( dppf ) in RuCl (PPh3)2(&#951;-C5H5) (80&#176;C, 16 h) afforded RuCl ( dppf )(&#951;-C5H5), which was converted into the corresponding hydride and 1,2-bis( methoxycarbonyl )vinyl derivatives. Crystals of RuH ( dppf )(&#951;-C5H5) are triclinic, space group P&#299; with a 14.392(3), b 20.175(5), c 12.379(2)&#506;, &#945; 105.02(2),&#946; 109.73(2),&#947; 96.56(2)&#176; and Z 4. The structure was refined by a blocked-matrix least-squares procedure to R 0.055 and Rw 0.056 for 3917 reflections with I &#8805; 2.5&#963;(I). 
