
TY  - JOUR
A1  - Smith, G 
A1  - Oreilly, EJ 
A1  - Kennard, CHL 
A1  - Mak, TCW 
A1  - Yip, WH 
A1  - Chan, WH 
T1  - The Crystal and Molecular Structure of <I>catena</I>-{Aquabis[2-methyl-2-(phenylthio)-propanoato]cadmium(II) monohydrate}
JF  - Australian Journal of Chemistry
JO  - Aust. J. Chem.
Y1  - 1988
VL  - 41
IS  - 11
SP  - 1769
EP  - 1772
KW  - 
UR  - https://doi.org/10.1071/CH9881769 
N2  - The crystal structure of the cadmium complex of 2-methyl-2-(phenylthio) propanoic acid, [ Cd (C6H5SC(CH3)2CO2)2(H2O)]. H2O has been determined by X-ray diffration and refined to a residual R 0.051 for 2725 observed reflections. Crystals are orthorhombic, space group Pbca with a 10.819(2), b 9.030(1), c 47.24(2) A and Z 8. The stereochemistry about cadmium is distorted MO6S seven-coordinate with Cd -S 2.747(2)&#506; and a Cd -O range 2.277-2.491(5)&#506;. Bonds are from cadmium to a water, and to four oxygens from two bidentate carboxylate groups, one of which also forms a polymer link. The same carboxylate group is also involved in a five- membered (S,O) chelate ring. 
ER  -

